城市生活垃圾生物转化乙醇初探     

马会强  张兰英  刘娜  刘虹  李爽  赵喆 《吉林大学学报(地球科学版)》2007,37(5):993-997

针对生活垃圾中的可利用成分,经酶水解后,利用筛选酵母菌对水解液进行乙醇发酵。通过正交实验得出最优水解条件为:pH值为5.5、加入纤维素酶8 mg、淀粉酶6 mg、水5 mL,65℃水解40 min。确定AQ菌作为最优菌种进行乙醇发酵实验。分别选取接种量、pH值、温度等因素进行单因子实验,讨论其对乙醇产量的影响。条件实验中,每克干生活垃圾最大产乙醇量为148.37 mg。  相似文献   

双酶法制备低黏度辛烯基琥珀酸淀粉钠的工艺条件   总被引：4，自引：0，他引：4  

阳元娥  罗发兴  黄强  谭伟 《广东海洋大学学报》2004,24(4):49-53

对双酶法制备用作微胶囊壁材的低黏度辛烯基琥珀酸淀粉钠的工艺路线与工艺条件进行了研究。正交实验结果表明 ,在酯化淀粉乳质量浓度 2 0 %、每 g淀粉α 淀粉酶的用量为 6SKBU的条件下 ,影响产品性能的各因素中 ,糖化酶的用量对产品的DE值和流度的影响最大 ,各因素的重要性依次是 :糖化酶的用量、糖化酶作用时间、α 淀粉酶保温作用时间。最佳工艺条件是 :α 淀粉酶保温作用时间 4min ,每 g淀粉糖化酶用量 0 .2GAU ,糖化酶作用时间 2 .5h ,此时产品的DE值为 30 ,流度为 80左右  相似文献   

MECHANISM OF THE HYDROLYSIS OF ADENOSINE 5＇-TRIPHOSPHATE: A REGRESSION ANALYSIS OF KINETIC DATA     

D.BRYNNHIBBERT  JOHNP.B.SANDALL 《地理学报(英文版)》1989,(3)

Data of the hydrolysis of adenosine 5'-triphosphate have been re-evaluated using a computer program thatnumerically integrates the differential rate equations within a routine that optimizes rate coefficients givena suitable model and concentration versus time data. The model is tested by calculation of Hamilton R-values, the Fisher F-statistic, a sensitivity analysis,the standard errors on the rate coefficients and by constructing contour maps of the objective functionversus two rate coefficients. An optimization using only phosphate concentration data cannot distinguish between a model in whichadenosine 5'-monophosphate is formed predominantly directly with a molecule of pyrophosphate, andone in which it is formed via adenosine 5'-diphosphate. A more accurate set of rate coefficients iscalculated from existing data and the relative importance of the two paths determined.  相似文献   

即时合成层状双氢氧化物处理酸性大红GR染料实验研究   总被引：3，自引：0，他引：3  

庆承松  陈天虎  王志光  樊明德  陈岗  孙捷 《矿物学报》2006,26(1):8-14

印染废水是重要的工业污染源之一,研究新的印染废水脱色技术是水污染控制技术领域重要课题之一。以酸性大红GR为典型代表,初步研究了镁-铝盐水解共沉淀法即时合成层状双氢氧化物(LDH)处理阴离子型染料溶液的效果、影响因素和染料去除机理。结果表明,镁-铝盐水解共沉淀法即时合成LDH对酸性大红GR染料溶液有非常好的脱色效果,影响处理效果的主要因素是Mg/Al比和pH值。在pH值8.5~10.0,Mg/Al比2∶1~4∶1,都可以获得较好的净化效果,酸性大红GR染料浓度0.65 mmol/L时,染料去除率达99%。其净化机理是,当在染料溶液中投加Mg2 、Al2 溶解盐和NaOH时,Mg2 、Al3 水解共沉淀形成LDH的同时,染料阴离子以平衡LDH结构电荷的形式进入LDH结构层间,含有染料的LDH通过沉淀分离从溶液中去除。  相似文献   

The Removal of Dissolved Metals by Hydroxysulphate Precipitates during Oxidation and Neutralization of Acid Mine Waters, Iberian Pyrite Belt   总被引：4，自引：0，他引：4  

J. Sánchez España  E. López Pamo  E. Santofimia Pastor  J. Reyes Andrés  J. A. Martín Rubí 《Aquatic Geochemistry》2006,12(3):269-298

This study examines the removal of dissolved metals during the oxidation and neutralization of five acid mine drainage (AMD) waters from La Zarza, Lomero, Esperanza, Corta Atalaya and Poderosa mines (Iberian Pyrite Belt, Huelva, Spain). These waters were selected to cover the spectrum of pH (2.2–3.5) and chemical composition (e.g., 319–2,103 mg/L Fe; 2.85–33.3 g/L SO₄⁼) of the IPB mine waters. The experiments were conducted in the laboratory to simulate the geochemical evolution previously recognized in the field. This evolution includes two stages: (1) oxidation of dissolved Fe(II) followed by hydrolysis and precipitation of Fe(III), and (2) progressive pH increase during mixing with fresh waters. Fe(III) precipitates at pH < 3.5 (stages 1 and 2) in the form of schwertmannite, whereas Al precipitates during stage 2 at pH 5.0 in the form of several hydroxysulphates of variable composition (hydrobasaluminite, basaluminite, aluminite). During these stages, trace elements are totally or partially sorbed and/or coprecipitated at different rates depending basically on pH, as well as on the activity of the SO₄⁼ anion (which determines the speciation of metals). The general trend for the metals which are chiefly present as aqueous free cations (Pb²⁺, Zn²⁺, Cu²⁺, Cd²⁺, Mn²⁺, Co²⁺, Ni²⁺) is a progressive sorption at increasing pH. On the other hand, As and V (mainly present as anionic species) are completely scavenged during the oxidation stage at pH < 3.5. In waters with high activities (> 10⁻¹) of the SO ₄⁼ ion, some elements like Al, Zn, Cd, Pb and U can also form anionic bisulphate complexes and be significantly sorbed at pH < 5. The removal rates at pH 7.0 range from around 100% for As, V, Cu and U, and 60–80% for Pb, to less than 20% for Zn, Co, Ni and Mn. These processes of metal removal represent a significant mechanism of natural attenuation in the IPB.  相似文献   

北极海冰细菌产胞外酶及主要环境因子的初步研究   总被引：1，自引：3，他引：1       下载免费PDF全文

曾胤新  俞勇  涂雪梅  陈波  何剑锋 《极地研究》2003,15(4):303-309

覆盖在北极海洋上的广阔海冰为其内部生存的微生物群落提供了一个独特的生境。研究表明 ,大量海冰细菌能够分泌产生胞外酶 ,其中产蛋白或脂质水解酶细菌的比例远高于产多糖水解酶的细菌。温度、盐度是直接影响海冰细菌生存与活力的 2个主要环境因子。 76%的产酪蛋白酶海冰细菌为低温菌 ,菌株只能在 <35°C条件下生长 ;而 98%的酪蛋白酶最适作用温度≥ 35°C ,其中 62 %的酶最适作用温度≥ 45°C。几乎所有的产酪蛋白酶海冰细菌都耐盐或嗜盐  相似文献   

贵州红枫湖沉积物有机质的酶及微生物降解   总被引：8，自引：1，他引：8  

梁小兵  朱建明  刘丛强  魏中青  汪福顺  万国江  黄荣贵 《第四纪研究》2003,23(5):565-572

文章通过DNA、α-葡萄糖苷酶和硫酸盐还原菌等的变化,研究了贵州红枫湖沉积物中有机质的酶及微生物降解.有机质在微生物及其分泌的胞外酶的作用下被降解,在沉积物深度11cm以下被降解到相对较低的含量.DNA的分布表明表层9cm的沉积物深度内微生物的活动较为强烈,是微生物降解有机质的主要位置.α-葡萄糖苷酶在悬浮层含量最高,达0.75μmol/min*g干沉积物,提示有机质中的淀粉和糖原等物质在悬浮层降解较为激烈,被大量分解;随着沉积物深度的增加α-葡萄糖苷酶活性减弱,在有机质降解明显开始变缓的11cm沉积物中,α-葡萄糖苷酶活性已降低到0.17μmol/ming干沉积物.分子生物学的研究表明红枫湖沉积物表层7cm是硫酸盐还原菌的主要分布位置,结合有机质和SO_2-4含量的研究结果,提示红枫湖沉积物中SO_2-4不可能成为有机质氧化的主要电子受体,硫酸盐还原的限制因素也不是有机质供应.  相似文献   

Adsorption of Au(III) and Au(I) complexes on δ-MnO2     

Yong Ran  Jiamo Fu  R. J. Gilkes  R. W. Rate 《中国科学D辑(英文版)》1999,42(2):172-181

The sorption of AuCl₄ ⁻,AuCl₂ ⁻ and Au(S₂O₃)^3- on δ-MnO₂ was investigated at pH2–11.6, 0.01 mol/L and 0.1 mol/L NaNO₃ solutions. At pH 4 in two electrolyte strength solutions, Au sorption densities on δ-MnO₂ are 0.18–0.21 and 0.28μmoL/m² for AuCl₄ ⁻ and Au(S₂O₃)₂ ^3-, respectively, and the Au surface coverage is approximate to or lower than 1%. This adsorption of the two Au complexes decreases as the solution pH increases, which conforms to the sorption regularity of the anion on δ-MnO₂. The Au sorption decreases in the sequence of Au(S₂O₃)₂ ^3- >AuCl₄ ⁻ >AuC1₂ ⁻. The intrinsic equilibrium constants (logK ^int) of the three Au complexes are 1.17–2.7, much higher than those of Cu and Cd. The hydrolysis products of AuCl₄ ^- are preferentially adsorbed by δ-MnO₂ and the inner-sphere Au-surface complexes are formed on the surface. Project supported by the National Studying-abroad Foundation, the National Natural Science Foundation of China (Grant No. 49573200) and the Australian Mining Industry.  相似文献   

某花岗伟晶岩型铀矿床铀迁移沉淀机制探讨   总被引：1，自引：1，他引：1  

曾令交  金景福 《华东地质学院学报》1994,17(3):264-269

  相似文献   

福建火山岩型铀矿化特征及其形成机制     

曾本兰 《华东地质学院学报》2001,24(4):295-297

福建 地处我国东南沿海，火山岩分布面积广，火山岩型铀矿化类型多，包括火山沉积型、远温地下热水淋滤型、火山期后热液型、富铀次火山岩体热液交代型等。铀矿化表现为多形态、多产状、多部位和多期、 多阶段，矿物 组合简单等特征。赋铀火山岩普遍发育有水解作用，岩石水解后，铀含量增加5－8倍，而分散铀量则减少50－80％。表明火山岩系中铀的活化与岩石的水解作用关切密切。另外，区内火山岩型铀矿化均赋存于火山杂岩系中的反差效应场中，显示出火山杂岩系中的反差效应场与铀的矿化也有密切关系。从总体上看，水解活化、渗析对流和半封闭强反差是福建火山岩型铀矿化的重要成矿机制。  相似文献